A glycoluril dimer-triptycene hybrid receptor: Synthesis and molecular recognition properties

Wenjin Liu; Xiaoyong Lu; Zihui Meng; Lyle Isaacs

doi:10.1039/c8ob01575a

A glycoluril dimer-triptycene hybrid receptor: Synthesis and molecular recognition properties

Wenjin Liu
, Xiaoyong Lu
, Zihui Meng^*
, Lyle Isaacs

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The strategic combination of the methylene bridged glycoluril dimer and triptycene skeletons delivers acyclic water soluble hybrid receptor 1 which is analogous to cucurbit[6]uril. The molecular recognition properties of host 1 toward hydrophobic cationic guests are investigated in detail by a combination of ¹H NMR spectroscopy and isothermal titration calorimetry (ITC) studies. The fluorescence emission of 1 can be selectively and efficiently quenched upon the formation of 1·26 and 1·28 complexes.

Original language	English
Pages (from-to)	6499-6506
Number of pages	8
Journal	Organic and Biomolecular Chemistry
Volume	16
Issue number	35
DOIs	https://doi.org/10.1039/c8ob01575a
Publication status	Published - 2018

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abstract = "The strategic combination of the methylene bridged glycoluril dimer and triptycene skeletons delivers acyclic water soluble hybrid receptor 1 which is analogous to cucurbit[6]uril. The molecular recognition properties of host 1 toward hydrophobic cationic guests are investigated in detail by a combination of 1H NMR spectroscopy and isothermal titration calorimetry (ITC) studies. The fluorescence emission of 1 can be selectively and efficiently quenched upon the formation of 1·26 and 1·28 complexes.",

author = "Wenjin Liu and Xiaoyong Lu and Zihui Meng and Lyle Isaacs",

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AU - Liu, Wenjin

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AU - Meng, Zihui

AU - Isaacs, Lyle

PY - 2018

Y1 - 2018

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AB - The strategic combination of the methylene bridged glycoluril dimer and triptycene skeletons delivers acyclic water soluble hybrid receptor 1 which is analogous to cucurbit[6]uril. The molecular recognition properties of host 1 toward hydrophobic cationic guests are investigated in detail by a combination of 1H NMR spectroscopy and isothermal titration calorimetry (ITC) studies. The fluorescence emission of 1 can be selectively and efficiently quenched upon the formation of 1·26 and 1·28 complexes.

UR - https://www.scopus.com/pages/publications/85053559602

U2 - 10.1039/c8ob01575a

DO - 10.1039/c8ob01575a

M3 - Article

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AN - SCOPUS:85053559602

SN - 1477-0520

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EP - 6506

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 35

ER -

A glycoluril dimer-triptycene hybrid receptor: Synthesis and molecular recognition properties

Abstract

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