A glycoluril dimer-triptycene hybrid receptor: Synthesis and molecular recognition properties

Wenjin Liu; Xiaoyong Lu; Zihui Meng; Lyle Isaacs

doi:10.1039/c8ob01575a

A glycoluril dimer-triptycene hybrid receptor: Synthesis and molecular recognition properties

Wenjin Liu, Xiaoyong Lu, Zihui Meng^*, Lyle Isaacs

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The strategic combination of the methylene bridged glycoluril dimer and triptycene skeletons delivers acyclic water soluble hybrid receptor 1 which is analogous to cucurbit[6]uril. The molecular recognition properties of host 1 toward hydrophobic cationic guests are investigated in detail by a combination of ¹H NMR spectroscopy and isothermal titration calorimetry (ITC) studies. The fluorescence emission of 1 can be selectively and efficiently quenched upon the formation of 1·26 and 1·28 complexes.

Original language	English
Pages (from-to)	6499-6506
Number of pages	8
Journal	Organic and Biomolecular Chemistry
Volume	16
Issue number	35
DOIs	https://doi.org/10.1039/c8ob01575a
Publication status	Published - 2018

Access to Document

10.1039/c8ob01575a

Cite this

@article{6ebf7595f7894622a2691e9c50d650fe,

title = "A glycoluril dimer-triptycene hybrid receptor: Synthesis and molecular recognition properties",

abstract = "The strategic combination of the methylene bridged glycoluril dimer and triptycene skeletons delivers acyclic water soluble hybrid receptor 1 which is analogous to cucurbit[6]uril. The molecular recognition properties of host 1 toward hydrophobic cationic guests are investigated in detail by a combination of 1H NMR spectroscopy and isothermal titration calorimetry (ITC) studies. The fluorescence emission of 1 can be selectively and efficiently quenched upon the formation of 1·26 and 1·28 complexes.",

author = "Wenjin Liu and Xiaoyong Lu and Zihui Meng and Lyle Isaacs",

note = "Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry.",

year = "2018",

doi = "10.1039/c8ob01575a",

language = "English",

volume = "16",

pages = "6499--6506",

journal = "Organic and Biomolecular Chemistry",

issn = "1477-0520",

publisher = "Royal Society of Chemistry",

number = "35",

}

TY - JOUR

T1 - A glycoluril dimer-triptycene hybrid receptor

T2 - Synthesis and molecular recognition properties

AU - Liu, Wenjin

AU - Lu, Xiaoyong

AU - Meng, Zihui

AU - Isaacs, Lyle

PY - 2018

Y1 - 2018

N2 - The strategic combination of the methylene bridged glycoluril dimer and triptycene skeletons delivers acyclic water soluble hybrid receptor 1 which is analogous to cucurbit[6]uril. The molecular recognition properties of host 1 toward hydrophobic cationic guests are investigated in detail by a combination of 1H NMR spectroscopy and isothermal titration calorimetry (ITC) studies. The fluorescence emission of 1 can be selectively and efficiently quenched upon the formation of 1·26 and 1·28 complexes.

AB - The strategic combination of the methylene bridged glycoluril dimer and triptycene skeletons delivers acyclic water soluble hybrid receptor 1 which is analogous to cucurbit[6]uril. The molecular recognition properties of host 1 toward hydrophobic cationic guests are investigated in detail by a combination of 1H NMR spectroscopy and isothermal titration calorimetry (ITC) studies. The fluorescence emission of 1 can be selectively and efficiently quenched upon the formation of 1·26 and 1·28 complexes.

UR - http://www.scopus.com/inward/record.url?scp=85053559602&partnerID=8YFLogxK

U2 - 10.1039/c8ob01575a

DO - 10.1039/c8ob01575a

M3 - Article

C2 - 30155536

AN - SCOPUS:85053559602

SN - 1477-0520

VL - 16

SP - 6499

EP - 6506

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 35

ER -

A glycoluril dimer-triptycene hybrid receptor: Synthesis and molecular recognition properties

Abstract

Access to Document

Other files and links

Fingerprint

Cite this