A germanate built from a 68126 cavity cotemplated by an (H2O)16 cluster and 2-methylpiperazine

Qinhe Pan; Jiyang Li; Kirsten E. Christensen; Charlotte Bonneau; Xiaoyan Ren; Lei Shi; Junliang Sun; Xiaodong Zou; Guanghua Li; Jihong Yu; Ruren Xu

doi:10.1002/anie.200801375

A germanate built from a 6⁸12⁶ cavity cotemplated by an (H₂O)₁₆ cluster and 2-methylpiperazine

Qinhe Pan^*, Jiyang Li, Kirsten E. Christensen, Charlotte Bonneau, Xiaoyan Ren, Lei Shi, Junliang Sun, Xiaodong Zou, Guanghua Li, Jihong Yu, Ruren Xu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

65 Citations (Scopus)

Abstract

Totally tubular: A new tubular germanate is cotemplated by 2-methylpiperazine and an (H₂O)₁₆ cluster in a hydro(solvo)-thermal synthesis. The germanate features a large, highly symmetric 6⁸12⁶ cavity (see picture; yellow sphere) built from 12 Ge₇X₁₉ (X = O, OH, F) clusters (GeX₆ red, GeX₅ yellow, GeX₄ green). (Figure Presented).

Original language	English
Pages (from-to)	7868-7871
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	41
DOIs	https://doi.org/10.1002/anie.200801375
Publication status	Published - 29 Sept 2008
Externally published	Yes

Keywords

Cluster compounds
Germanates
Hydrogen bonds
Solvothermal synthesis
Tubular structures

Access to Document

10.1002/anie.200801375

Cite this

@article{837d0695bd7a4b6c9a27f84c1417ade8,

title = "A germanate built from a 68126 cavity cotemplated by an (H2O)16 cluster and 2-methylpiperazine",

abstract = "Totally tubular: A new tubular germanate is cotemplated by 2-methylpiperazine and an (H2O)16 cluster in a hydro(solvo)-thermal synthesis. The germanate features a large, highly symmetric 68126 cavity (see picture; yellow sphere) built from 12 Ge7X19 (X = O, OH, F) clusters (GeX6 red, GeX5 yellow, GeX4 green). (Figure Presented).",

keywords = "Cluster compounds, Germanates, Hydrogen bonds, Solvothermal synthesis, Tubular structures",

author = "Qinhe Pan and Jiyang Li and Christensen, {Kirsten E.} and Charlotte Bonneau and Xiaoyan Ren and Lei Shi and Junliang Sun and Xiaodong Zou and Guanghua Li and Jihong Yu and Ruren Xu",

year = "2008",

month = sep,

day = "29",

doi = "10.1002/anie.200801375",

language = "English",

volume = "47",

pages = "7868--7871",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "41",

}

TY - JOUR

T1 - A germanate built from a 68126 cavity cotemplated by an (H2O)16 cluster and 2-methylpiperazine

AU - Pan, Qinhe

AU - Li, Jiyang

AU - Christensen, Kirsten E.

AU - Bonneau, Charlotte

AU - Ren, Xiaoyan

AU - Shi, Lei

AU - Sun, Junliang

AU - Zou, Xiaodong

AU - Li, Guanghua

AU - Yu, Jihong

AU - Xu, Ruren

PY - 2008/9/29

Y1 - 2008/9/29

N2 - Totally tubular: A new tubular germanate is cotemplated by 2-methylpiperazine and an (H2O)16 cluster in a hydro(solvo)-thermal synthesis. The germanate features a large, highly symmetric 68126 cavity (see picture; yellow sphere) built from 12 Ge7X19 (X = O, OH, F) clusters (GeX6 red, GeX5 yellow, GeX4 green). (Figure Presented).

AB - Totally tubular: A new tubular germanate is cotemplated by 2-methylpiperazine and an (H2O)16 cluster in a hydro(solvo)-thermal synthesis. The germanate features a large, highly symmetric 68126 cavity (see picture; yellow sphere) built from 12 Ge7X19 (X = O, OH, F) clusters (GeX6 red, GeX5 yellow, GeX4 green). (Figure Presented).

KW - Cluster compounds

KW - Germanates

KW - Hydrogen bonds

KW - Solvothermal synthesis

KW - Tubular structures

UR - http://www.scopus.com/inward/record.url?scp=54749128907&partnerID=8YFLogxK

U2 - 10.1002/anie.200801375

DO - 10.1002/anie.200801375

M3 - Article

AN - SCOPUS:54749128907

SN - 1433-7851

VL - 47

SP - 7868

EP - 7871

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 41

ER -

A germanate built from a 6⁸12⁶ cavity cotemplated by an (H₂O)₁₆ cluster and 2-methylpiperazine

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this