A Dual Photochemically Active Molecule Showing Distributable Reactivity Based on Anion-Assisted Coordination Assembly

Ya Jun Zhang; Cheng Chen; Li Xuan Cai; Xiao Dong Yang; Jie Zhang

doi:10.1021/acs.inorgchem.7b01497

A Dual Photochemically Active Molecule Showing Distributable Reactivity Based on Anion-Assisted Coordination Assembly

Ya Jun Zhang
, Cheng Chen
, Li Xuan Cai
, Xiao Dong Yang
, Jie Zhang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

CAS - Fujian Institute of Research on the Structure of Matter
Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Distributable reactivity of a dual photochemically active molecule functionalized by a carboxyl coordination unit has been achieved based on anion-assisted coordination assembly. The anions induce the photoactive ligand to align at different orientations in three-dimensional metal-organic frameworks, thus allowing the supramolecular systems to show photocycloaddition with simultaneous luminescence transformation or undergo photoinduced electron transfer accompanied by coloration-decoloration under alternating light and thermal stimuli.

Original language	English
Pages (from-to)	10529-10534
Number of pages	6
Journal	Inorganic Chemistry
Volume	56
Issue number	17
DOIs	https://doi.org/10.1021/acs.inorgchem.7b01497
Publication status	Published - 5 Sept 2017

Access to Document

10.1021/acs.inorgchem.7b01497

Cite this

@article{2272a17ceee24e7ca19d19642d469834,

title = "A Dual Photochemically Active Molecule Showing Distributable Reactivity Based on Anion-Assisted Coordination Assembly",

abstract = "Distributable reactivity of a dual photochemically active molecule functionalized by a carboxyl coordination unit has been achieved based on anion-assisted coordination assembly. The anions induce the photoactive ligand to align at different orientations in three-dimensional metal-organic frameworks, thus allowing the supramolecular systems to show photocycloaddition with simultaneous luminescence transformation or undergo photoinduced electron transfer accompanied by coloration-decoloration under alternating light and thermal stimuli.",

author = "Zhang, \{Ya Jun\} and Cheng Chen and Cai, \{Li Xuan\} and Yang, \{Xiao Dong\} and Jie Zhang",

note = "Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",

year = "2017",

month = sep,

day = "5",

doi = "10.1021/acs.inorgchem.7b01497",

language = "English",

volume = "56",

pages = "10529--10534",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "17",

}

TY - JOUR

T1 - A Dual Photochemically Active Molecule Showing Distributable Reactivity Based on Anion-Assisted Coordination Assembly

AU - Zhang, Ya Jun

AU - Chen, Cheng

AU - Cai, Li Xuan

AU - Yang, Xiao Dong

AU - Zhang, Jie

PY - 2017/9/5

Y1 - 2017/9/5

N2 - Distributable reactivity of a dual photochemically active molecule functionalized by a carboxyl coordination unit has been achieved based on anion-assisted coordination assembly. The anions induce the photoactive ligand to align at different orientations in three-dimensional metal-organic frameworks, thus allowing the supramolecular systems to show photocycloaddition with simultaneous luminescence transformation or undergo photoinduced electron transfer accompanied by coloration-decoloration under alternating light and thermal stimuli.

AB - Distributable reactivity of a dual photochemically active molecule functionalized by a carboxyl coordination unit has been achieved based on anion-assisted coordination assembly. The anions induce the photoactive ligand to align at different orientations in three-dimensional metal-organic frameworks, thus allowing the supramolecular systems to show photocycloaddition with simultaneous luminescence transformation or undergo photoinduced electron transfer accompanied by coloration-decoloration under alternating light and thermal stimuli.

UR - https://www.scopus.com/pages/publications/85028927399

U2 - 10.1021/acs.inorgchem.7b01497

DO - 10.1021/acs.inorgchem.7b01497

M3 - Article

C2 - 28809554

AN - SCOPUS:85028927399

SN - 0020-1669

VL - 56

SP - 10529

EP - 10534

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 17

ER -

A Dual Photochemically Active Molecule Showing Distributable Reactivity Based on Anion-Assisted Coordination Assembly

Abstract

Access to Document

Other files and links

Fingerprint

Cite this