A composite based on {VO3}nn- chain containing two different types of organic ligands

Xinfang Wang; Guiling Guo; Yanqing Xu; Changwen Hu

doi:10.14233/ajchem.2013.13505

A composite based on {VO3}_n^n- chain containing two different types of organic ligands

Xinfang Wang
, Guiling Guo
, Yanqing Xu
, Changwen Hu^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The composite compound, [Cu(1,10-phen)(en)H₂O][Cu(en)2]0. 5[V₃O₉] (1,10-phen = 1,10-phenanthroline, en = ethylenediamine) (1) has been prepared by solution diffusion method. Compound 1 consists of one 1D {VO3}_n^n- chain formed by corner-sharing VO4 tetrahedra and two different types of cations [Cu(1,10-phen)(en)H2O] ²⁺ and [Cu(en)2]²⁺. The adjacent 1D {VO3}_n ^n- chain are further bridged by [Cu(en)2]2+ complexes through Cu⋯O weak interactions to form a 2D network.

Original language	English
Pages (from-to)	3033-3035
Number of pages	3
Journal	Asian Journal of Chemistry
Volume	25
Issue number	6
DOIs	https://doi.org/10.14233/ajchem.2013.13505
Publication status	Published - 2013
Externally published	Yes

Keywords

Cluster
Network
Polyoxometalates
Polyoxovanadates

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10.14233/ajchem.2013.13505

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@article{959f1c71cae942de93c77d7e45c1b49e,

title = "A composite based on \{VO3\}nn- chain containing two different types of organic ligands",

abstract = "The composite compound, [Cu(1,10-phen)(en)H2O][Cu(en)2]0. 5[V3O9] (1,10-phen = 1,10-phenanthroline, en = ethylenediamine) (1) has been prepared by solution diffusion method. Compound 1 consists of one 1D \{VO3\}nn- chain formed by corner-sharing VO4 tetrahedra and two different types of cations [Cu(1,10-phen)(en)H2O] 2+ and [Cu(en)2]2+. The adjacent 1D \{VO3\}n n- chain are further bridged by [Cu(en)2]2+ complexes through Cu⋯O weak interactions to form a 2D network.",

keywords = "Cluster, Network, Polyoxometalates, Polyoxovanadates",

author = "Xinfang Wang and Guiling Guo and Yanqing Xu and Changwen Hu",

year = "2013",

doi = "10.14233/ajchem.2013.13505",

language = "English",

volume = "25",

pages = "3033--3035",

journal = "Asian Journal of Chemistry",

issn = "0970-7077",

publisher = "Asian Publication Corporation",

number = "6",

}

TY - JOUR

T1 - A composite based on {VO3}nn- chain containing two different types of organic ligands

AU - Wang, Xinfang

AU - Guo, Guiling

AU - Xu, Yanqing

AU - Hu, Changwen

PY - 2013

Y1 - 2013

N2 - The composite compound, [Cu(1,10-phen)(en)H2O][Cu(en)2]0. 5[V3O9] (1,10-phen = 1,10-phenanthroline, en = ethylenediamine) (1) has been prepared by solution diffusion method. Compound 1 consists of one 1D {VO3}nn- chain formed by corner-sharing VO4 tetrahedra and two different types of cations [Cu(1,10-phen)(en)H2O] 2+ and [Cu(en)2]2+. The adjacent 1D {VO3}n n- chain are further bridged by [Cu(en)2]2+ complexes through Cu⋯O weak interactions to form a 2D network.

AB - The composite compound, [Cu(1,10-phen)(en)H2O][Cu(en)2]0. 5[V3O9] (1,10-phen = 1,10-phenanthroline, en = ethylenediamine) (1) has been prepared by solution diffusion method. Compound 1 consists of one 1D {VO3}nn- chain formed by corner-sharing VO4 tetrahedra and two different types of cations [Cu(1,10-phen)(en)H2O] 2+ and [Cu(en)2]2+. The adjacent 1D {VO3}n n- chain are further bridged by [Cu(en)2]2+ complexes through Cu⋯O weak interactions to form a 2D network.

KW - Cluster

KW - Network

KW - Polyoxometalates

KW - Polyoxovanadates

UR - https://www.scopus.com/pages/publications/84875190996

U2 - 10.14233/ajchem.2013.13505

DO - 10.14233/ajchem.2013.13505

M3 - Article

AN - SCOPUS:84875190996

SN - 0970-7077

VL - 25

SP - 3033

EP - 3035

JO - Asian Journal of Chemistry

JF - Asian Journal of Chemistry

IS - 6

ER -

A composite based on {VO3}_n^n- chain containing two different types of organic ligands

Abstract

Keywords

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