A 3D manganese coordination polymer [Mn3(IMDC) 2(H2O)4] constructed from [Mn 2(IMDC)2(H2O)2] layers and [Mn(H2O)2] pillars (IMDC = 4,5-imidazoledicarboxylate)

Man Bo Zhang; Yong Mei Chen; Shou Tian Zheng; Guo Yu Yang

doi:10.1002/ejic.200500883

A 3D manganese coordination polymer [Mn₃(IMDC) ₂(H₂O)₄] constructed from [Mn ₂(IMDC)₂(H₂O)₂] layers and [Mn(H₂O)₂] pillars (IMDC = 4,5-imidazoledicarboxylate)

Man Bo Zhang, Yong Mei Chen, Shou Tian Zheng, Guo Yu Yang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

57 Citations (Scopus)

Abstract

A novel three-dimensional coordination polymer [Mn₃(IMDC) ₂(H₂O)₄] (1) (IMDC = 4,5- imidazoledicarboxylate), consisting of [Mn₂(IMDC)₂(H ₂O)₂] layers and [Mn(H₂O)₂] pillars, was synthesized hydrothermally and characterized by IR spectroscopy, elemental analysis, TGA, and magnetic measurements. It is the first example of a 3D framework containing 4,5-imidazoledicarboxylate in the family of manganese complexes. Variable-temperature magnetic susceptibility measurements show a weak antiferromagnetic coupling interaction between the Mn^II ions of the dimeric units.

Original language	English
Pages (from-to)	1423-1428
Number of pages	6
Journal	European Journal of Inorganic Chemistry
Issue number	7
DOIs	https://doi.org/10.1002/ejic.200500883
Publication status	Published - 3 Apr 2006
Externally published	Yes

Keywords

Carboxylate ligands
Coordination polymers
Hydrothermal synthesis
Manganese

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10.1002/ejic.200500883

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title = "A 3D manganese coordination polymer [Mn3(IMDC) 2(H2O)4] constructed from [Mn 2(IMDC)2(H2O)2] layers and [Mn(H2O)2] pillars (IMDC = 4,5-imidazoledicarboxylate)",

abstract = "A novel three-dimensional coordination polymer [Mn3(IMDC) 2(H2O)4] (1) (IMDC = 4,5- imidazoledicarboxylate), consisting of [Mn2(IMDC)2(H 2O)2] layers and [Mn(H2O)2] pillars, was synthesized hydrothermally and characterized by IR spectroscopy, elemental analysis, TGA, and magnetic measurements. It is the first example of a 3D framework containing 4,5-imidazoledicarboxylate in the family of manganese complexes. Variable-temperature magnetic susceptibility measurements show a weak antiferromagnetic coupling interaction between the MnII ions of the dimeric units.",

keywords = "Carboxylate ligands, Coordination polymers, Hydrothermal synthesis, Manganese",

author = "Zhang, \{Man Bo\} and Chen, \{Yong Mei\} and Zheng, \{Shou Tian\} and Yang, \{Guo Yu\}",

year = "2006",

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day = "3",

doi = "10.1002/ejic.200500883",

language = "English",

pages = "1423--1428",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

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T1 - A 3D manganese coordination polymer [Mn3(IMDC) 2(H2O)4] constructed from [Mn 2(IMDC)2(H2O)2] layers and [Mn(H2O)2] pillars (IMDC = 4,5-imidazoledicarboxylate)

AU - Zhang, Man Bo

AU - Chen, Yong Mei

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2006/4/3

Y1 - 2006/4/3

N2 - A novel three-dimensional coordination polymer [Mn3(IMDC) 2(H2O)4] (1) (IMDC = 4,5- imidazoledicarboxylate), consisting of [Mn2(IMDC)2(H 2O)2] layers and [Mn(H2O)2] pillars, was synthesized hydrothermally and characterized by IR spectroscopy, elemental analysis, TGA, and magnetic measurements. It is the first example of a 3D framework containing 4,5-imidazoledicarboxylate in the family of manganese complexes. Variable-temperature magnetic susceptibility measurements show a weak antiferromagnetic coupling interaction between the MnII ions of the dimeric units.

AB - A novel three-dimensional coordination polymer [Mn3(IMDC) 2(H2O)4] (1) (IMDC = 4,5- imidazoledicarboxylate), consisting of [Mn2(IMDC)2(H 2O)2] layers and [Mn(H2O)2] pillars, was synthesized hydrothermally and characterized by IR spectroscopy, elemental analysis, TGA, and magnetic measurements. It is the first example of a 3D framework containing 4,5-imidazoledicarboxylate in the family of manganese complexes. Variable-temperature magnetic susceptibility measurements show a weak antiferromagnetic coupling interaction between the MnII ions of the dimeric units.

KW - Carboxylate ligands

KW - Coordination polymers

KW - Hydrothermal synthesis

KW - Manganese

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DO - 10.1002/ejic.200500883

M3 - Article

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JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

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A 3D manganese coordination polymer [Mn₃(IMDC) ₂(H₂O)₄] constructed from [Mn ₂(IMDC)₂(H₂O)₂] layers and [Mn(H₂O)₂] pillars (IMDC = 4,5-imidazoledicarboxylate)

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Keywords

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