A 3D heteropolynuclear network with 4,6-connected (44 · 62)(48 · 66 · 8) topology: Synthesis, structure, thermal and magnetic properties

Pang Kuan Chen; Yun Xia Che; Ji Min Zheng

doi:10.1016/j.inoche.2006.10.015

A 3D heteropolynuclear network with 4,6-connected (4⁴ · 6²)(4⁸ · 6⁶ · 8) topology: Synthesis, structure, thermal and magnetic properties

Pang Kuan Chen
, Yun Xia Che
, Ji Min Zheng^*

^*Corresponding author for this work

Nankai University

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

This paper describes a novel heteropolynuclear coordination polymer [Cd₄Co₂(m-BDC)₆(HIm)₄]_n (1) (m-H₂BDC = 1,3-benzenedicarboxylic acid, Him = imidazole), which has been hydrothermally prepared and characterized by single-crystal X-ray diffraction, IR, ICP, XRPD, TGA, DSC, and element analysis. The overall architecture is constructed from alternate Co(II) and Cd layers arranged in ABAB mode, and affords a three-dimensional (3D) 4,6-conneccted (4⁴ · 6²)(4⁸ · 6⁶ · 8) topological network. Furthermore, magnetic property of 1 has also been studied in the temperature range of 5-300 K.

Original language	English
Pages (from-to)	187-190
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	10
Issue number	2
DOIs	https://doi.org/10.1016/j.inoche.2006.10.015
Publication status	Published - Feb 2007
Externally published	Yes

Keywords

4,6-Connected topology
Alternate layer
Heteropolynuclear
Hydrothermal synthesis
Magnetic property
Thermal property

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10.1016/j.inoche.2006.10.015

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title = "A 3D heteropolynuclear network with 4,6-connected (44 · 62)(48 · 66 · 8) topology: Synthesis, structure, thermal and magnetic properties",

abstract = "This paper describes a novel heteropolynuclear coordination polymer [Cd4Co2(m-BDC)6(HIm)4]n (1) (m-H2BDC = 1,3-benzenedicarboxylic acid, Him = imidazole), which has been hydrothermally prepared and characterized by single-crystal X-ray diffraction, IR, ICP, XRPD, TGA, DSC, and element analysis. The overall architecture is constructed from alternate Co(II) and Cd layers arranged in ABAB mode, and affords a three-dimensional (3D) 4,6-conneccted (44 · 62)(48 · 66 · 8) topological network. Furthermore, magnetic property of 1 has also been studied in the temperature range of 5-300 K.",

keywords = "4,6-Connected topology, Alternate layer, Heteropolynuclear, Hydrothermal synthesis, Magnetic property, Thermal property",

author = "Chen, \{Pang Kuan\} and Che, \{Yun Xia\} and Zheng, \{Ji Min\}",

year = "2007",

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doi = "10.1016/j.inoche.2006.10.015",

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volume = "10",

pages = "187--190",

journal = "Inorganic Chemistry Communications",

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TY - JOUR

T1 - A 3D heteropolynuclear network with 4,6-connected (44 · 62)(48 · 66 · 8) topology

T2 - Synthesis, structure, thermal and magnetic properties

AU - Chen, Pang Kuan

AU - Che, Yun Xia

AU - Zheng, Ji Min

PY - 2007/2

Y1 - 2007/2

N2 - This paper describes a novel heteropolynuclear coordination polymer [Cd4Co2(m-BDC)6(HIm)4]n (1) (m-H2BDC = 1,3-benzenedicarboxylic acid, Him = imidazole), which has been hydrothermally prepared and characterized by single-crystal X-ray diffraction, IR, ICP, XRPD, TGA, DSC, and element analysis. The overall architecture is constructed from alternate Co(II) and Cd layers arranged in ABAB mode, and affords a three-dimensional (3D) 4,6-conneccted (44 · 62)(48 · 66 · 8) topological network. Furthermore, magnetic property of 1 has also been studied in the temperature range of 5-300 K.

AB - This paper describes a novel heteropolynuclear coordination polymer [Cd4Co2(m-BDC)6(HIm)4]n (1) (m-H2BDC = 1,3-benzenedicarboxylic acid, Him = imidazole), which has been hydrothermally prepared and characterized by single-crystal X-ray diffraction, IR, ICP, XRPD, TGA, DSC, and element analysis. The overall architecture is constructed from alternate Co(II) and Cd layers arranged in ABAB mode, and affords a three-dimensional (3D) 4,6-conneccted (44 · 62)(48 · 66 · 8) topological network. Furthermore, magnetic property of 1 has also been studied in the temperature range of 5-300 K.

KW - 4,6-Connected topology

KW - Alternate layer

KW - Heteropolynuclear

KW - Hydrothermal synthesis

KW - Magnetic property

KW - Thermal property

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DO - 10.1016/j.inoche.2006.10.015

M3 - Article

AN - SCOPUS:33846200013

SN - 1387-7003

VL - 10

SP - 187

EP - 190

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 2

ER -

A 3D heteropolynuclear network with 4,6-connected (4⁴ · 6²)(4⁸ · 6⁶ · 8) topology: Synthesis, structure, thermal and magnetic properties

Abstract

Keywords

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