A 3D coordination framework based on linkages of nanosized hydroxo lanthanide clusters and copper centers by isonicotinate ligands

Man Bo Zhang; Jie Zhang; Shou Tian Zheng; Guo Yu Yang

doi:10.1002/anie.200461424

A 3D coordination framework based on linkages of nanosized hydroxo lanthanide clusters and copper centers by isonicotinate ligands

Man Bo Zhang, Jie Zhang, Shou Tian Zheng, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

347 Citations (Scopus)

Abstract

Lanthanide oxides as sources of lanthanides provided 3D coordination polymers under hydrothermal conditions in which distinct [Ln₁₄, (μ₆-O)(μ₃-OH)₂₀(H₂O) ₈]²⁰⁺ (Ln = Y, Gd, Dy) clusters are linked to two different types of copper centers through isonicotinate ligands. The unprecedented 3D network topology of. these isostructural compounds is exemplified for Ln = Gd in the picture, which reveals the presence of 1D channels along the c axis.

Original language	English
Pages (from-to)	1385-1388
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	44
Issue number	9
DOIs	https://doi.org/10.1002/anie.200461424
Publication status	Published - 18 Feb 2005
Externally published	Yes

Keywords

Bridging ligands
Cluster compounds
Copper
Hydrothermal synthesis
Lanthanides

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10.1002/anie.200461424

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abstract = "Lanthanide oxides as sources of lanthanides provided 3D coordination polymers under hydrothermal conditions in which distinct [Ln14, (μ6-O)(μ3-OH)20(H2O) 8]20+ (Ln = Y, Gd, Dy) clusters are linked to two different types of copper centers through isonicotinate ligands. The unprecedented 3D network topology of. these isostructural compounds is exemplified for Ln = Gd in the picture, which reveals the presence of 1D channels along the c axis.",

keywords = "Bridging ligands, Cluster compounds, Copper, Hydrothermal synthesis, Lanthanides",

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AU - Zhang, Man Bo

AU - Zhang, Jie

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2005/2/18

Y1 - 2005/2/18

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AB - Lanthanide oxides as sources of lanthanides provided 3D coordination polymers under hydrothermal conditions in which distinct [Ln14, (μ6-O)(μ3-OH)20(H2O) 8]20+ (Ln = Y, Gd, Dy) clusters are linked to two different types of copper centers through isonicotinate ligands. The unprecedented 3D network topology of. these isostructural compounds is exemplified for Ln = Gd in the picture, which reveals the presence of 1D channels along the c axis.

KW - Bridging ligands

KW - Cluster compounds

KW - Copper

KW - Hydrothermal synthesis

KW - Lanthanides

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EP - 1388

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JF - Angewandte Chemie - International Edition

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ER -

A 3D coordination framework based on linkages of nanosized hydroxo lanthanide clusters and copper centers by isonicotinate ligands

Abstract

Keywords

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