A 2D azine-linked covalent organic framework for gas storage applications

Zhongping Li; Xiao Feng; Yongcun Zou; Yuwei Zhang; Hong Xia; Xiaoming Liu; Ying Mu

doi:10.1039/c4cc05665e

A 2D azine-linked covalent organic framework for gas storage applications

Zhongping Li
, Xiao Feng
, Yongcun Zou
, Yuwei Zhang
, Hong Xia
, Xiaoming Liu^*
, Ying Mu

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Jilin University

Research output: Contribution to journal › Article › peer-review

400 Citations (Scopus)

Abstract

A new azine-linked covalent organic framework, ACOF-1, was synthesized by condensation of hydrazine hydrate and 1,3,5-triformylbenzene under solvothermal conditions. ACOF-1 has a high surface area and a small pore size, and it can store up to 177 mg g⁻¹ of CO₂, 9.9 mg g⁻¹ of H₂, and 11.5 mg g⁻¹ of CH₄, at 273 K and 1 bar, with high selectivity towards CO₂ over N₂ and CH₄.

Original language	English
Pages (from-to)	13825-13828
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	89
DOIs	https://doi.org/10.1039/c4cc05665e
Publication status	Published - 14 Oct 2014

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abstract = "A new azine-linked covalent organic framework, ACOF-1, was synthesized by condensation of hydrazine hydrate and 1,3,5-triformylbenzene under solvothermal conditions. ACOF-1 has a high surface area and a small pore size, and it can store up to 177 mg g−1 of CO2, 9.9 mg g−1 of H2, and 11.5 mg g−1 of CH4, at 273 K and 1 bar, with high selectivity towards CO2 over N2 and CH4.",

author = "Zhongping Li and Xiao Feng and Yongcun Zou and Yuwei Zhang and Hong Xia and Xiaoming Liu and Ying Mu",

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AU - Li, Zhongping

AU - Feng, Xiao

AU - Zou, Yongcun

AU - Zhang, Yuwei

AU - Xia, Hong

AU - Liu, Xiaoming

AU - Mu, Ying

PY - 2014/10/14

Y1 - 2014/10/14

N2 - A new azine-linked covalent organic framework, ACOF-1, was synthesized by condensation of hydrazine hydrate and 1,3,5-triformylbenzene under solvothermal conditions. ACOF-1 has a high surface area and a small pore size, and it can store up to 177 mg g−1 of CO2, 9.9 mg g−1 of H2, and 11.5 mg g−1 of CH4, at 273 K and 1 bar, with high selectivity towards CO2 over N2 and CH4.

AB - A new azine-linked covalent organic framework, ACOF-1, was synthesized by condensation of hydrazine hydrate and 1,3,5-triformylbenzene under solvothermal conditions. ACOF-1 has a high surface area and a small pore size, and it can store up to 177 mg g−1 of CO2, 9.9 mg g−1 of H2, and 11.5 mg g−1 of CH4, at 273 K and 1 bar, with high selectivity towards CO2 over N2 and CH4.

UR - https://www.scopus.com/pages/publications/84908133590

U2 - 10.1039/c4cc05665e

DO - 10.1039/c4cc05665e

M3 - Article

AN - SCOPUS:84908133590

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VL - 50

SP - 13825

EP - 13828

JO - Chemical Communications

JF - Chemical Communications

IS - 89

ER -

A 2D azine-linked covalent organic framework for gas storage applications

Abstract

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