7-Iodo-3,3-diphenyloctahydrobenzofuran

Muhammad Sohail; Wang Yao-Feng; Wang Qi; Fu Xue Chen

doi:10.1107/S1600536813007563

7-Iodo-3,3-diphenyloctahydrobenzofuran

Muhammad Sohail
, Wang Yao-Feng
, Wang Qi
, Fu Xue Chen^*

^*Corresponding author for this work

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The title compound, C₂₀H₂₁IO, was synthesized by cyclohaloetherification of 2-(cyclohex-2-enyl)-2,2-diphenylethanol in CH ₂Cl₂, and crystallized with two independent molecules in the asymmetric unit. The six-membered cyclohexane ring adopts a chair conformation, while the five-membered ring adopts an envelope conformation with the fused C atom opposite the O atom as the flap in each case [displacements of the flap atoms = 0.6813 (3) and 0.6679 (3) Å]. In the crystal, molecules are linked via pairs of C-H⋯π interactions, forming inversion dimers.

Original language	English
Pages (from-to)	o585
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	69
Issue number	4
DOIs	https://doi.org/10.1107/S1600536813007563
Publication status	Published - Apr 2013
Externally published	Yes

Access to Document

10.1107/S1600536813007563

Cite this

@article{847a111eb1844ab4a3dfc68f7ccccc12,

title = "7-Iodo-3,3-diphenyloctahydrobenzofuran",

abstract = "The title compound, C20H21IO, was synthesized by cyclohaloetherification of 2-(cyclohex-2-enyl)-2,2-diphenylethanol in CH 2Cl2, and crystallized with two independent molecules in the asymmetric unit. The six-membered cyclohexane ring adopts a chair conformation, while the five-membered ring adopts an envelope conformation with the fused C atom opposite the O atom as the flap in each case [displacements of the flap atoms = 0.6813 (3) and 0.6679 (3) {\AA}]. In the crystal, molecules are linked via pairs of C-H⋯π interactions, forming inversion dimers.",

author = "Muhammad Sohail and Wang Yao-Feng and Wang Qi and Chen, \{Fu Xue\}",

year = "2013",

month = apr,

doi = "10.1107/S1600536813007563",

language = "English",

volume = "69",

pages = "o585",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "4",

}

TY - JOUR

T1 - 7-Iodo-3,3-diphenyloctahydrobenzofuran

AU - Sohail, Muhammad

AU - Yao-Feng, Wang

AU - Qi, Wang

AU - Chen, Fu Xue

PY - 2013/4

Y1 - 2013/4

N2 - The title compound, C20H21IO, was synthesized by cyclohaloetherification of 2-(cyclohex-2-enyl)-2,2-diphenylethanol in CH 2Cl2, and crystallized with two independent molecules in the asymmetric unit. The six-membered cyclohexane ring adopts a chair conformation, while the five-membered ring adopts an envelope conformation with the fused C atom opposite the O atom as the flap in each case [displacements of the flap atoms = 0.6813 (3) and 0.6679 (3) Å]. In the crystal, molecules are linked via pairs of C-H⋯π interactions, forming inversion dimers.

AB - The title compound, C20H21IO, was synthesized by cyclohaloetherification of 2-(cyclohex-2-enyl)-2,2-diphenylethanol in CH 2Cl2, and crystallized with two independent molecules in the asymmetric unit. The six-membered cyclohexane ring adopts a chair conformation, while the five-membered ring adopts an envelope conformation with the fused C atom opposite the O atom as the flap in each case [displacements of the flap atoms = 0.6813 (3) and 0.6679 (3) Å]. In the crystal, molecules are linked via pairs of C-H⋯π interactions, forming inversion dimers.

UR - https://www.scopus.com/pages/publications/84875983013

U2 - 10.1107/S1600536813007563

DO - 10.1107/S1600536813007563

M3 - Article

AN - SCOPUS:84875983013

SN - 1600-5368

VL - 69

SP - o585

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -

7-Iodo-3,3-diphenyloctahydrobenzofuran

Abstract

Access to Document

Other files and links

Fingerprint

Cite this