4-Chloro-3,5-dinitropyrazole: A precursor for promising insensitive energetic compounds

Chunlin He; Jiaheng Zhang; Damon A. Parrish; Jean'Ne M. Shreeve

doi:10.1039/c2ta01359b

4-Chloro-3,5-dinitropyrazole: A precursor for promising insensitive energetic compounds

Chunlin He, Jiaheng Zhang, Damon A. Parrish, Jean'Ne M. Shreeve^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

125 Citations (Scopus)

Abstract

A series of 3,5-dinitropyrazole derivatives was prepared from 4-chloro-3,5-dinitropyrazole in good yields and characterized by IR, ¹H, and ¹³C NMR (some cases ¹⁵N NMR) spectroscopy, elemental analysis, and DSC. The structures of 7 and 13 were confirmed by single crystal X-ray diffraction. The impact sensitivity was determined using a standard BAM method, and detonation properties were obtained using experimental densities and calculated heats of formation.

Original language	English
Pages (from-to)	2863-2868
Number of pages	6
Journal	Journal of Materials Chemistry A
Volume	1
Issue number	8
DOIs	https://doi.org/10.1039/c2ta01359b
Publication status	Published - 28 Feb 2013
Externally published	Yes

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abstract = "A series of 3,5-dinitropyrazole derivatives was prepared from 4-chloro-3,5-dinitropyrazole in good yields and characterized by IR, 1H, and 13C NMR (some cases 15N NMR) spectroscopy, elemental analysis, and DSC. The structures of 7 and 13 were confirmed by single crystal X-ray diffraction. The impact sensitivity was determined using a standard BAM method, and detonation properties were obtained using experimental densities and calculated heats of formation.",

author = "Chunlin He and Jiaheng Zhang and Parrish, \{Damon A.\} and Shreeve, \{Jean'Ne M.\}",

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T2 - A precursor for promising insensitive energetic compounds

AU - He, Chunlin

AU - Zhang, Jiaheng

AU - Parrish, Damon A.

AU - Shreeve, Jean'Ne M.

PY - 2013/2/28

Y1 - 2013/2/28

N2 - A series of 3,5-dinitropyrazole derivatives was prepared from 4-chloro-3,5-dinitropyrazole in good yields and characterized by IR, 1H, and 13C NMR (some cases 15N NMR) spectroscopy, elemental analysis, and DSC. The structures of 7 and 13 were confirmed by single crystal X-ray diffraction. The impact sensitivity was determined using a standard BAM method, and detonation properties were obtained using experimental densities and calculated heats of formation.

AB - A series of 3,5-dinitropyrazole derivatives was prepared from 4-chloro-3,5-dinitropyrazole in good yields and characterized by IR, 1H, and 13C NMR (some cases 15N NMR) spectroscopy, elemental analysis, and DSC. The structures of 7 and 13 were confirmed by single crystal X-ray diffraction. The impact sensitivity was determined using a standard BAM method, and detonation properties were obtained using experimental densities and calculated heats of formation.

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U2 - 10.1039/c2ta01359b

DO - 10.1039/c2ta01359b

M3 - Article

AN - SCOPUS:84876566247

SN - 2050-7488

VL - 1

SP - 2863

EP - 2868

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

IS - 8

ER -

4-Chloro-3,5-dinitropyrazole: A precursor for promising insensitive energetic compounds

Abstract

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