3D Printed Polyimide Nanocomposite Aerogels for Electromagnetic Interference Shielding and Thermal Management

Tingting Wu; Michal Ganobjak; Gilberto Siqueira; Zhihui Zeng; Mengmeng Li; Ekaterina Filimonova; Somayeh Saghamanesh; Anne Bonnin; Deeptanshu Sivaraman; Joshua Yip; Lei Li; Hui Wu; Gustav Nyström; Wim J. Malfait; Shanyu Zhao

doi:10.1002/admt.202202155

3D Printed Polyimide Nanocomposite Aerogels for Electromagnetic Interference Shielding and Thermal Management

Tingting Wu
, Michal Ganobjak
, Gilberto Siqueira^*
, Zhihui Zeng^*
, Mengmeng Li
, Ekaterina Filimonova
, Somayeh Saghamanesh
, Anne Bonnin
, Deeptanshu Sivaraman
, Joshua Yip
, Lei Li
, Hui Wu
, Gustav Nyström
, Wim J. Malfait^*
, Shanyu Zhao^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

47 Citations (Scopus)

Abstract

Aerogels were listed among the top ten emerging technologies in chemistry by IUPAC in 2022. Their record-breaking properties sparked the emergence of a thriving insulation market, but solutions are sought to promote additional applications. A 3D assembly process based on direct ink writing of “aerogel-in-aerogel” nanocomposites is presented. The printed polyimide-silica aerogels are non-brittle (E = 6.7 MPa) with a super-insulating thermal conductivity (20.3 mW m⁻¹ K⁻¹) and high thermal stability (T_5wt% 447 °C). In addition, they display excellent low-loss dielectric properties and microwave transmission over all relevant communication bands and can be functionalized for electromagnetic interference (EMI) shielding. The high shape-fidelity printing, combined with laser-induced etching of thermally conductive graphene layers, enable precise thermal management for portable electronics or maintain an extreme temperature gradient (−40 to +50°C) across a millimeter-scale partition.

Original language	English
Article number	2202155
Journal	Advanced Materials Technologies
Volume	8
Issue number	14
DOIs	https://doi.org/10.1002/admt.202202155
Publication status	Published - 24 Jul 2023
Externally published	Yes

Keywords

additive manufacturing
aerogels
dielectric properties
polyimide
thermal management

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10.1002/admt.202202155

Cite this

Wu, T., Ganobjak, M., Siqueira, G., Zeng, Z., Li, M., Filimonova, E., Saghamanesh, S., Bonnin, A., Sivaraman, D., Yip, J., Li, L., Wu, H., Nyström, G., Malfait, W. J., & Zhao, S. (2023). 3D Printed Polyimide Nanocomposite Aerogels for Electromagnetic Interference Shielding and Thermal Management. Advanced Materials Technologies, 8(14), Article 2202155. https://doi.org/10.1002/admt.202202155

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title = "3D Printed Polyimide Nanocomposite Aerogels for Electromagnetic Interference Shielding and Thermal Management",

abstract = "Aerogels were listed among the top ten emerging technologies in chemistry by IUPAC in 2022. Their record-breaking properties sparked the emergence of a thriving insulation market, but solutions are sought to promote additional applications. A 3D assembly process based on direct ink writing of “aerogel-in-aerogel” nanocomposites is presented. The printed polyimide-silica aerogels are non-brittle (E = 6.7 MPa) with a super-insulating thermal conductivity (20.3 mW m−1 K−1) and high thermal stability (T5wt\% 447 °C). In addition, they display excellent low-loss dielectric properties and microwave transmission over all relevant communication bands and can be functionalized for electromagnetic interference (EMI) shielding. The high shape-fidelity printing, combined with laser-induced etching of thermally conductive graphene layers, enable precise thermal management for portable electronics or maintain an extreme temperature gradient (−40 to +50°C) across a millimeter-scale partition.",

keywords = "additive manufacturing, aerogels, dielectric properties, polyimide, thermal management",

author = "Tingting Wu and Michal Ganobjak and Gilberto Siqueira and Zhihui Zeng and Mengmeng Li and Ekaterina Filimonova and Somayeh Saghamanesh and Anne Bonnin and Deeptanshu Sivaraman and Joshua Yip and Lei Li and Hui Wu and Gustav Nystr{\"o}m and Malfait, \{Wim J.\} and Shanyu Zhao",

note = "Publisher Copyright: {\textcopyright} 2023 The Authors. Advanced Materials Technologies published by Wiley-VCH GmbH.",

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doi = "10.1002/admt.202202155",

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Wu, T, Ganobjak, M, Siqueira, G, Zeng, Z, Li, M, Filimonova, E, Saghamanesh, S, Bonnin, A, Sivaraman, D, Yip, J, Li, L, Wu, H, Nyström, G, Malfait, WJ & Zhao, S 2023, '3D Printed Polyimide Nanocomposite Aerogels for Electromagnetic Interference Shielding and Thermal Management', Advanced Materials Technologies, vol. 8, no. 14, 2202155. https://doi.org/10.1002/admt.202202155

TY - JOUR

T1 - 3D Printed Polyimide Nanocomposite Aerogels for Electromagnetic Interference Shielding and Thermal Management

AU - Wu, Tingting

AU - Ganobjak, Michal

AU - Siqueira, Gilberto

AU - Zeng, Zhihui

AU - Li, Mengmeng

AU - Filimonova, Ekaterina

AU - Saghamanesh, Somayeh

AU - Bonnin, Anne

AU - Sivaraman, Deeptanshu

AU - Yip, Joshua

AU - Li, Lei

AU - Wu, Hui

AU - Nyström, Gustav

AU - Malfait, Wim J.

AU - Zhao, Shanyu

PY - 2023/7/24

Y1 - 2023/7/24

N2 - Aerogels were listed among the top ten emerging technologies in chemistry by IUPAC in 2022. Their record-breaking properties sparked the emergence of a thriving insulation market, but solutions are sought to promote additional applications. A 3D assembly process based on direct ink writing of “aerogel-in-aerogel” nanocomposites is presented. The printed polyimide-silica aerogels are non-brittle (E = 6.7 MPa) with a super-insulating thermal conductivity (20.3 mW m−1 K−1) and high thermal stability (T5wt% 447 °C). In addition, they display excellent low-loss dielectric properties and microwave transmission over all relevant communication bands and can be functionalized for electromagnetic interference (EMI) shielding. The high shape-fidelity printing, combined with laser-induced etching of thermally conductive graphene layers, enable precise thermal management for portable electronics or maintain an extreme temperature gradient (−40 to +50°C) across a millimeter-scale partition.

AB - Aerogels were listed among the top ten emerging technologies in chemistry by IUPAC in 2022. Their record-breaking properties sparked the emergence of a thriving insulation market, but solutions are sought to promote additional applications. A 3D assembly process based on direct ink writing of “aerogel-in-aerogel” nanocomposites is presented. The printed polyimide-silica aerogels are non-brittle (E = 6.7 MPa) with a super-insulating thermal conductivity (20.3 mW m−1 K−1) and high thermal stability (T5wt% 447 °C). In addition, they display excellent low-loss dielectric properties and microwave transmission over all relevant communication bands and can be functionalized for electromagnetic interference (EMI) shielding. The high shape-fidelity printing, combined with laser-induced etching of thermally conductive graphene layers, enable precise thermal management for portable electronics or maintain an extreme temperature gradient (−40 to +50°C) across a millimeter-scale partition.

KW - additive manufacturing

KW - aerogels

KW - dielectric properties

KW - polyimide

KW - thermal management

UR - https://www.scopus.com/pages/publications/85152079927

U2 - 10.1002/admt.202202155

DO - 10.1002/admt.202202155

M3 - Article

AN - SCOPUS:85152079927

SN - 2365-709X

VL - 8

JO - Advanced Materials Technologies

JF - Advanced Materials Technologies

IS - 14

M1 - 2202155

ER -

3D Printed Polyimide Nanocomposite Aerogels for Electromagnetic Interference Shielding and Thermal Management

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Keywords

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