2-(2-Hydr-oxy-1-naphthyl-diazen-yl)-pyridinium [1-(2-pyridyldiazen-yl)-2- naphtholato-3 N,N′,O]tris-(thio-cyanato-N)chromium(III) methanol solvate

Tian Fu Liu; Hong Yan Lv; Bang Tun Zhao; Jian Ge Wang

doi:10.1107/S1600536807040688

2-(2-Hydr-oxy-1-naphthyl-diazen-yl)-pyridinium [1-(2-pyridyldiazen-yl)-2- naphtholato-³ N,N′,O]tris-(thio-cyanato-N)chromium(III) methanol solvate

Tian Fu Liu^*
, Hong Yan Lv
, Bang Tun Zhao
, Jian Ge Wang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Ministry of Education of China
Beijing Institute of Technology
Department of Chemistry
Luoyang Normal University

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

In the title compound, (C15H12N3O)[Cr(C15H10N3O)(NCS)3]·CH4O, the Cr^III atom is coordinated by two N atoms and one O atom from the tridentate 1-(2-pyridyldiazen-yl)-2-naphthol-ate (PAN) ligand and three N atoms from thio-cyanate ions in a distorted octa-hedral arrangement. Another uncoordinated and protonated PAN mol-ecule and a methanol solvent mol-ecule are present in the asymmetric unit. The crystal packing is stabilized by π-π inter-actions [centroid-centroid separation 3.594 (4) Å] and O - H⋯N and O - H⋯S hydrogen bonds.

Original language	English
Pages (from-to)	m2406
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	63
Issue number	9
DOIs	https://doi.org/10.1107/S1600536807040688
Publication status	Published - 29 Aug 2007

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@article{aa329b80006a4190a9692f01a1fdf4e4,

title = "2-(2-Hydr-oxy-1-naphthyl-diazen-yl)-pyridinium [1-(2-pyridyldiazen-yl)-2- naphtholato-3 N,N′,O]tris-(thio-cyanato-N)chromium(III) methanol solvate",

abstract = "In the title compound, (C15H12N3O)[Cr(C15H10N3O)(NCS)3]·CH4O, the CrIII atom is coordinated by two N atoms and one O atom from the tridentate 1-(2-pyridyldiazen-yl)-2-naphthol-ate (PAN) ligand and three N atoms from thio-cyanate ions in a distorted octa-hedral arrangement. Another uncoordinated and protonated PAN mol-ecule and a methanol solvent mol-ecule are present in the asymmetric unit. The crystal packing is stabilized by π-π inter-actions [centroid-centroid separation 3.594 (4) {\AA}] and O - H⋯N and O - H⋯S hydrogen bonds.",

author = "Liu, \{Tian Fu\} and Lv, \{Hong Yan\} and Zhao, \{Bang Tun\} and Wang, \{Jian Ge\}",

year = "2007",

month = aug,

day = "29",

doi = "10.1107/S1600536807040688",

language = "English",

volume = "63",

pages = "m2406",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "9",

}

2-(2-Hydr-oxy-1-naphthyl-diazen-yl)-pyridinium [1-(2-pyridyldiazen-yl)-2- naphtholato-³ N,N′,O]tris-(thio-cyanato-N)chromium(III) methanol solvate. / Liu, Tian Fu; Lv, Hong Yan; Zhao, Bang Tun et al.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 63, No. 9, 29.08.2007, p. m2406.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - 2-(2-Hydr-oxy-1-naphthyl-diazen-yl)-pyridinium [1-(2-pyridyldiazen-yl)-2- naphtholato-3 N,N′,O]tris-(thio-cyanato-N)chromium(III) methanol solvate

AU - Liu, Tian Fu

AU - Lv, Hong Yan

AU - Zhao, Bang Tun

AU - Wang, Jian Ge

PY - 2007/8/29

Y1 - 2007/8/29

N2 - In the title compound, (C15H12N3O)[Cr(C15H10N3O)(NCS)3]·CH4O, the CrIII atom is coordinated by two N atoms and one O atom from the tridentate 1-(2-pyridyldiazen-yl)-2-naphthol-ate (PAN) ligand and three N atoms from thio-cyanate ions in a distorted octa-hedral arrangement. Another uncoordinated and protonated PAN mol-ecule and a methanol solvent mol-ecule are present in the asymmetric unit. The crystal packing is stabilized by π-π inter-actions [centroid-centroid separation 3.594 (4) Å] and O - H⋯N and O - H⋯S hydrogen bonds.

AB - In the title compound, (C15H12N3O)[Cr(C15H10N3O)(NCS)3]·CH4O, the CrIII atom is coordinated by two N atoms and one O atom from the tridentate 1-(2-pyridyldiazen-yl)-2-naphthol-ate (PAN) ligand and three N atoms from thio-cyanate ions in a distorted octa-hedral arrangement. Another uncoordinated and protonated PAN mol-ecule and a methanol solvent mol-ecule are present in the asymmetric unit. The crystal packing is stabilized by π-π inter-actions [centroid-centroid separation 3.594 (4) Å] and O - H⋯N and O - H⋯S hydrogen bonds.

UR - https://www.scopus.com/pages/publications/34548417526

U2 - 10.1107/S1600536807040688

DO - 10.1107/S1600536807040688

M3 - Article

AN - SCOPUS:34548417526

SN - 1600-5368

VL - 63

SP - m2406

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 9

ER -

2-(2-Hydr-oxy-1-naphthyl-diazen-yl)-pyridinium [1-(2-pyridyldiazen-yl)-2- naphtholato-³ N,N′,O]tris-(thio-cyanato-N)chromium(III) methanol solvate

Abstract

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