1D tube, 2D layer, and 3D framework derived from a new series of metal(II) - 5-Aminodiacetic isophthalate coordination polymers

Yanqing Xu; Daqiang Yuan; Benlai Wu; Lei Han; Mingyan Wu; Feilong Jiang; Maochun Hong

doi:10.1021/cg0506774

1D tube, 2D layer, and 3D framework derived from a new series of metal(II) - 5-Aminodiacetic isophthalate coordination polymers

Yanqing Xu
, Daqiang Yuan
, Benlai Wu
, Lei Han
, Mingyan Wu
, Feilong Jiang^*
, Maochun Hong

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

135 Citations (Scopus)

Abstract

Three novel coordination polymers, [Cu₂(adip)(H ₂O)4]_n·nH₂O (1), [Co₃(Hadip) ₂(H₂O)₆]_n·2nH₂O (2), and [Zn₇(adip)₄(H₂O)₁₀K ₂(H₂O)₂]_n·4nH₂O (3), were solvothermally synthesized by adopting a new type of multicarboxylate ligand, H₄adip (H₄adip = 5-aminodiacetic isophthalic acid). Compound 1 features a 1D tube-like structure, compound 2 shows novel 2D (3,4)-connected nets, and compound 3 possesses an interesting 3D architecture, all of which possess channels hosting guest water molecules. A particular interest of the adip^4- ligand is its propensity to bind metal ions forming various metallocycles, which could be viewed as the basic building blocks in the construction of supramolecular frameworks. Thermogravimetric analyses (TGA) were performed on compounds 1, 2, and 3. Variable-temperature magnetic susceptibility of 2 was investigated. An intense blue luminescence with an emission band peaking at 454 nm observed for 3 may result from ligand-to-metal charge transfer (LMCT).

Original language	English
Pages (from-to)	1168-1174
Number of pages	7
Journal	Crystal Growth and Design
Volume	6
Issue number	5
DOIs	https://doi.org/10.1021/cg0506774
Publication status	Published - May 2006
Externally published	Yes

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@article{31de631150ae4e80ac8c854141fef3ca,

title = "1D tube, 2D layer, and 3D framework derived from a new series of metal(II) - 5-Aminodiacetic isophthalate coordination polymers",

abstract = "Three novel coordination polymers, [Cu2(adip)(H 2O)4]n·nH2O (1), [Co3(Hadip) 2(H2O)6]n·2nH2O (2), and [Zn7(adip)4(H2O)10K 2(H2O)2]n·4nH2O (3), were solvothermally synthesized by adopting a new type of multicarboxylate ligand, H4adip (H4adip = 5-aminodiacetic isophthalic acid). Compound 1 features a 1D tube-like structure, compound 2 shows novel 2D (3,4)-connected nets, and compound 3 possesses an interesting 3D architecture, all of which possess channels hosting guest water molecules. A particular interest of the adip4- ligand is its propensity to bind metal ions forming various metallocycles, which could be viewed as the basic building blocks in the construction of supramolecular frameworks. Thermogravimetric analyses (TGA) were performed on compounds 1, 2, and 3. Variable-temperature magnetic susceptibility of 2 was investigated. An intense blue luminescence with an emission band peaking at 454 nm observed for 3 may result from ligand-to-metal charge transfer (LMCT).",

author = "Yanqing Xu and Daqiang Yuan and Benlai Wu and Lei Han and Mingyan Wu and Feilong Jiang and Maochun Hong",

year = "2006",

month = may,

doi = "10.1021/cg0506774",

language = "English",

volume = "6",

pages = "1168--1174",

journal = "Crystal Growth and Design",

issn = "1528-7483",

publisher = "American Chemical Society",

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TY - JOUR

T1 - 1D tube, 2D layer, and 3D framework derived from a new series of metal(II) - 5-Aminodiacetic isophthalate coordination polymers

AU - Xu, Yanqing

AU - Yuan, Daqiang

AU - Wu, Benlai

AU - Han, Lei

AU - Wu, Mingyan

AU - Jiang, Feilong

AU - Hong, Maochun

PY - 2006/5

Y1 - 2006/5

N2 - Three novel coordination polymers, [Cu2(adip)(H 2O)4]n·nH2O (1), [Co3(Hadip) 2(H2O)6]n·2nH2O (2), and [Zn7(adip)4(H2O)10K 2(H2O)2]n·4nH2O (3), were solvothermally synthesized by adopting a new type of multicarboxylate ligand, H4adip (H4adip = 5-aminodiacetic isophthalic acid). Compound 1 features a 1D tube-like structure, compound 2 shows novel 2D (3,4)-connected nets, and compound 3 possesses an interesting 3D architecture, all of which possess channels hosting guest water molecules. A particular interest of the adip4- ligand is its propensity to bind metal ions forming various metallocycles, which could be viewed as the basic building blocks in the construction of supramolecular frameworks. Thermogravimetric analyses (TGA) were performed on compounds 1, 2, and 3. Variable-temperature magnetic susceptibility of 2 was investigated. An intense blue luminescence with an emission band peaking at 454 nm observed for 3 may result from ligand-to-metal charge transfer (LMCT).

AB - Three novel coordination polymers, [Cu2(adip)(H 2O)4]n·nH2O (1), [Co3(Hadip) 2(H2O)6]n·2nH2O (2), and [Zn7(adip)4(H2O)10K 2(H2O)2]n·4nH2O (3), were solvothermally synthesized by adopting a new type of multicarboxylate ligand, H4adip (H4adip = 5-aminodiacetic isophthalic acid). Compound 1 features a 1D tube-like structure, compound 2 shows novel 2D (3,4)-connected nets, and compound 3 possesses an interesting 3D architecture, all of which possess channels hosting guest water molecules. A particular interest of the adip4- ligand is its propensity to bind metal ions forming various metallocycles, which could be viewed as the basic building blocks in the construction of supramolecular frameworks. Thermogravimetric analyses (TGA) were performed on compounds 1, 2, and 3. Variable-temperature magnetic susceptibility of 2 was investigated. An intense blue luminescence with an emission band peaking at 454 nm observed for 3 may result from ligand-to-metal charge transfer (LMCT).

UR - https://www.scopus.com/pages/publications/33744771655

U2 - 10.1021/cg0506774

DO - 10.1021/cg0506774

M3 - Article

AN - SCOPUS:33744771655

SN - 1528-7483

VL - 6

SP - 1168

EP - 1174

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 5

ER -

1D tube, 2D layer, and 3D framework derived from a new series of metal(II) - 5-Aminodiacetic isophthalate coordination polymers

Abstract

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