TY - JOUR
T1 - Two novel self-interpenetrating 3D iron(II) coordination frameworks
T2 - Synthesis, spectroscopic and structural characterizations with magnetic properties
AU - Setifi, Zouaoui
AU - Addala, Abderazzak
AU - Tao, Jun
AU - Wannarit, Nanthawat
AU - Glidewell, Christopher
AU - Setifi, Fatima
AU - Youngme, Sujittra
N1 - Publisher Copyright:
© 2016 Elsevier B.V. All rights reserved.
PY - 2016/6
Y1 - 2016/6
N2 - Two novel self-interpenetrating 3D Fe(II) coordination frameworks namely {Fe(4,4′-bpy)[Ag2(CN)3]2}n (I) and {Fe(4,4′-bpy)[Ag(CN)2]2[AgCN]2}n (II) have been synthesized and fully characterized. The 3D architectures and degree of interpenetration of these coordination frameworks were significantly affected by silver(I) cyanide species. The crystal structure of I presents 4-fold interpenetrating 3D framework with 4,4′-bpy and [Ag2(CN)3]- species. While, that of II constructed by 4,4′-bpy and two different silver(I) cyanide species, AgCN and [Ag(CN)2]- resulting to 2-fold interpenetrating 3D framework. The stability and rigidity of both coordination frameworks are mainly supported dominantly by AgI ⋯ AgI interactions. Their magnetic properties exhibit high spin behavior.
AB - Two novel self-interpenetrating 3D Fe(II) coordination frameworks namely {Fe(4,4′-bpy)[Ag2(CN)3]2}n (I) and {Fe(4,4′-bpy)[Ag(CN)2]2[AgCN]2}n (II) have been synthesized and fully characterized. The 3D architectures and degree of interpenetration of these coordination frameworks were significantly affected by silver(I) cyanide species. The crystal structure of I presents 4-fold interpenetrating 3D framework with 4,4′-bpy and [Ag2(CN)3]- species. While, that of II constructed by 4,4′-bpy and two different silver(I) cyanide species, AgCN and [Ag(CN)2]- resulting to 2-fold interpenetrating 3D framework. The stability and rigidity of both coordination frameworks are mainly supported dominantly by AgI ⋯ AgI interactions. Their magnetic properties exhibit high spin behavior.
KW - Ag ⋯ Ag
KW - Fe(II) coordination frameworks
KW - Magnetic properties
KW - Self-interpenetrate
UR - http://www.scopus.com/inward/record.url?scp=84964981914&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2016.04.005
DO - 10.1016/j.inoche.2016.04.005
M3 - Article
AN - SCOPUS:84964981914
SN - 1387-7003
VL - 68
SP - 80
EP - 84
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
ER -