Chirality from substitution: Enantiomer separation via a modified metal-organic framework

Jingshu Zhao, Haiwei Li, Yuzhen Han, Rui Li, Xuesong Ding, Xiao Feng*, Bo Wang

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

83 引用 (Scopus)

摘要

A microporous MOF structure, d-his-ZIF-8, with a chiral environment was synthesized via a simple ligand in situ substitution (LIS) of 2-methyl imidazolate (mIm) with d-histidine. These chiral MOF composites show exceptional selective separation capability for racemic alanine and glutamic acid, with an ee value of 78.52% and 79.44%, respectively.

源语言英语
页(从-至)12145-12148
页数4
期刊Journal of Materials Chemistry A
3
23
DOI
出版状态已出版 - 21 6月 2015

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