Three new aluminoborates: from 1D tube to 3D framework

Juan Chen; Chong An Chen; Peng Yun Zhang; Guo Yu Yang

doi:10.1039/d3dt02374e

Three new aluminoborates: from 1D tube to 3D framework

Juan Chen, Chong An Chen, Peng Yun Zhang, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Three new aluminoborates (ABOs) KCs[Al{B₅O₉(OH)}{BO(OH)₂} (1), K_0.5Cs[Al{B₅O₁₀}_1/2{BO₂(OH)}] (2), and Cs_1.5[Al{B₅O₁₀}_1/2{BO₂(OH)}] (3) have been made under solvothermal conditions. 1 features a 1D tube constructed by the alternation of [B₅O₉(OH)]⁴⁻ clusters and AlO₄ units, onto which the [BO(OH)₂]⁻ triangles are grafted. To further construct higher dimensional structures based on the structure 1, solvents were adjusted for high basicity, resulting in the formations of the 3D ABO frameworks 2 and 3. 2 and 3 are isostructural and built from [B₅O₁₀]⁵⁻ clusters, AlO₄ tetrahedra and [BO₂(OH)]²⁻ triangles, in which [B₅O₁₀]⁵⁻ clusters are bridged by AlO₄ tetrahedra to produce a 2D ABO layer with 14-membered ring (MR) windows, and the [BO₂(OH)]²⁻ triangles act as the linkers to bridge the adjacent ABO layers to form 3D ABO frameworks containing eight types of channels. UV-vis diffuse reflectance spectra indicate that 1, 2, and 3 have potential applications in deep ultraviolet (DUV) regions.

Original language	English
Pages (from-to)	12845-12851
Number of pages	7
Journal	Dalton Transactions
Volume	52
Issue number	36
DOIs	https://doi.org/10.1039/d3dt02374e
Publication status	Published - 21 Aug 2023

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title = "Three new aluminoborates: from 1D tube to 3D framework",

abstract = "Three new aluminoborates (ABOs) KCs[Al{B5O9(OH)}{BO(OH)2} (1), K0.5Cs[Al{B5O10}1/2{BO2(OH)}] (2), and Cs1.5[Al{B5O10}1/2{BO2(OH)}] (3) have been made under solvothermal conditions. 1 features a 1D tube constructed by the alternation of [B5O9(OH)]4− clusters and AlO4 units, onto which the [BO(OH)2]− triangles are grafted. To further construct higher dimensional structures based on the structure 1, solvents were adjusted for high basicity, resulting in the formations of the 3D ABO frameworks 2 and 3. 2 and 3 are isostructural and built from [B5O10]5− clusters, AlO4 tetrahedra and [BO2(OH)]2− triangles, in which [B5O10]5− clusters are bridged by AlO4 tetrahedra to produce a 2D ABO layer with 14-membered ring (MR) windows, and the [BO2(OH)]2− triangles act as the linkers to bridge the adjacent ABO layers to form 3D ABO frameworks containing eight types of channels. UV-vis diffuse reflectance spectra indicate that 1, 2, and 3 have potential applications in deep ultraviolet (DUV) regions.",

author = "Juan Chen and Chen, {Chong An} and Zhang, {Peng Yun} and Yang, {Guo Yu}",

note = "Publisher Copyright: {\textcopyright} 2023 The Royal Society of Chemistry.",

year = "2023",

month = aug,

day = "21",

doi = "10.1039/d3dt02374e",

language = "English",

volume = "52",

pages = "12845--12851",

journal = "Dalton Transactions",

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AU - Chen, Juan

AU - Chen, Chong An

AU - Zhang, Peng Yun

AU - Yang, Guo Yu

PY - 2023/8/21

Y1 - 2023/8/21

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AB - Three new aluminoborates (ABOs) KCs[Al{B5O9(OH)}{BO(OH)2} (1), K0.5Cs[Al{B5O10}1/2{BO2(OH)}] (2), and Cs1.5[Al{B5O10}1/2{BO2(OH)}] (3) have been made under solvothermal conditions. 1 features a 1D tube constructed by the alternation of [B5O9(OH)]4− clusters and AlO4 units, onto which the [BO(OH)2]− triangles are grafted. To further construct higher dimensional structures based on the structure 1, solvents were adjusted for high basicity, resulting in the formations of the 3D ABO frameworks 2 and 3. 2 and 3 are isostructural and built from [B5O10]5− clusters, AlO4 tetrahedra and [BO2(OH)]2− triangles, in which [B5O10]5− clusters are bridged by AlO4 tetrahedra to produce a 2D ABO layer with 14-membered ring (MR) windows, and the [BO2(OH)]2− triangles act as the linkers to bridge the adjacent ABO layers to form 3D ABO frameworks containing eight types of channels. UV-vis diffuse reflectance spectra indicate that 1, 2, and 3 have potential applications in deep ultraviolet (DUV) regions.

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ER -

Three new aluminoborates: from 1D tube to 3D framework

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