Thermal and photoinduced valence tautomerism of a chain compound

Liqin Chen, Rongjia Wei, Jun Tao*, Rongbin Huang, Lansun Zheng

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

15 Citations (Scopus)

Abstract

Herein reported is an example of one-dimensional coordination polymer [Co II(3,5-DBsq) 2(dpg)]•(3,5-H 2DBcat) 2 (1) (3,5-DBsq = 3,5-di-tert-butylsemiquinonate, 3,5-H 2DBcat = 3,5-di-tert-butyl-benzene-1,2-diol, dpg = meso-alpha,beta-di(4-pyridyl)glycol) capable of undergoing thermal and photoinduced valence tautomeric transitions.

Original languageEnglish
Pages (from-to)1037-1041
Number of pages5
JournalScience China Chemistry
Volume55
Issue number6
DOIs
Publication statusPublished - Jun 2012
Externally publishedYes

Keywords

  • cobalt(II)
  • coordination polymer
  • photo excitation
  • valence tautomerism

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