The effects of pressure on valence tautomeric transitions of dinuclear cobalt complexes

Bao Li; Feng Lei Yang; Jun Tao; Osamu Sato; Rong Bin Huang; Lan Sun Zheng

doi:10.1039/b814944e

The effects of pressure on valence tautomeric transitions of dinuclear cobalt complexes

Bao Li, Feng Lei Yang, Jun Tao^*, Osamu Sato, Rong Bin Huang, Lan Sun Zheng

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

The effects of pressure on valence trautomeric transition behavior of two complexes, [{Co(tpa)}₂(dhbq)]·(PF₆)₃ (I·(PF₆)₃) and [{Co(dpqa)}₂(dhbq)] ·(PF₆)₃ (II·(PF₆)₃) (tpa = tris(2-pyridylmethyl)amine, dpqa = di(2-pyridylmethyl)-N-(quinolin-2- ylmethyl)amine and dhbq = deprotonated 2,5-dihydroxy-1,4-benzoquinone), in the light of changes of magnetic susceptibilities were investigated; the results show that external pressure makes the SC + ET transition process of the two complexes into a general SC process only.

Original language	English
Pages (from-to)	6019-6021
Number of pages	3
Journal	Chemical Communications
Issue number	45
DOIs	https://doi.org/10.1039/b814944e
Publication status	Published - 2008
Externally published	Yes

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title = "The effects of pressure on valence tautomeric transitions of dinuclear cobalt complexes",

abstract = "The effects of pressure on valence trautomeric transition behavior of two complexes, [{Co(tpa)}2(dhbq)]·(PF6)3 (I·(PF6)3) and [{Co(dpqa)}2(dhbq)] ·(PF6)3 (II·(PF6)3) (tpa = tris(2-pyridylmethyl)amine, dpqa = di(2-pyridylmethyl)-N-(quinolin-2- ylmethyl)amine and dhbq = deprotonated 2,5-dihydroxy-1,4-benzoquinone), in the light of changes of magnetic susceptibilities were investigated; the results show that external pressure makes the SC + ET transition process of the two complexes into a general SC process only.",

author = "Bao Li and Yang, {Feng Lei} and Jun Tao and Osamu Sato and Huang, {Rong Bin} and Zheng, {Lan Sun}",

year = "2008",

doi = "10.1039/b814944e",

language = "English",

pages = "6019--6021",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - The effects of pressure on valence tautomeric transitions of dinuclear cobalt complexes

AU - Li, Bao

AU - Yang, Feng Lei

AU - Tao, Jun

AU - Sato, Osamu

AU - Huang, Rong Bin

AU - Zheng, Lan Sun

PY - 2008

Y1 - 2008

N2 - The effects of pressure on valence trautomeric transition behavior of two complexes, [{Co(tpa)}2(dhbq)]·(PF6)3 (I·(PF6)3) and [{Co(dpqa)}2(dhbq)] ·(PF6)3 (II·(PF6)3) (tpa = tris(2-pyridylmethyl)amine, dpqa = di(2-pyridylmethyl)-N-(quinolin-2- ylmethyl)amine and dhbq = deprotonated 2,5-dihydroxy-1,4-benzoquinone), in the light of changes of magnetic susceptibilities were investigated; the results show that external pressure makes the SC + ET transition process of the two complexes into a general SC process only.

AB - The effects of pressure on valence trautomeric transition behavior of two complexes, [{Co(tpa)}2(dhbq)]·(PF6)3 (I·(PF6)3) and [{Co(dpqa)}2(dhbq)] ·(PF6)3 (II·(PF6)3) (tpa = tris(2-pyridylmethyl)amine, dpqa = di(2-pyridylmethyl)-N-(quinolin-2- ylmethyl)amine and dhbq = deprotonated 2,5-dihydroxy-1,4-benzoquinone), in the light of changes of magnetic susceptibilities were investigated; the results show that external pressure makes the SC + ET transition process of the two complexes into a general SC process only.

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U2 - 10.1039/b814944e

DO - 10.1039/b814944e

M3 - Article

AN - SCOPUS:56749154080

SN - 1359-7345

SP - 6019

EP - 6021

JO - Chemical Communications

JF - Chemical Communications

IS - 45

ER -

The effects of pressure on valence tautomeric transitions of dinuclear cobalt complexes

Abstract

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