Synthesis and characterization of hexaalkylguanidinium TADC energetic ionic liquids

Zhi Yong Gan; Chun Peng Chai; Yun Jun Luo; Na Li

Synthesis and characterization of hexaalkylguanidinium TADC energetic ionic liquids

Zhi Yong Gan, Chun Peng Chai^*, Yun Jun Luo, Na Li

^*Corresponding author for this work

School of Material Science and Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

Four kinds of hexaalkylguanidinium 4,5-dicyano-1,2,3-triazole([C _n-guan][TADC], n=3,4,5,6) energetic ionic liquids were synthesized by an ion exchange technique.Their structures were identified by IR and ¹HNMR.Their density, solubility, thermal properties were studied.Their structures were identifed by IR, 'HNMR, solubility were tested in common organic solvents, density were measured by surface interfacial tersion meter, thermal properties were studied through TG, DSC method.The results showed that hexaalkylguanidinium TADC ionic liquids had good solubility in most of organic solvents. The maximum decomposition temperature was about 370°C, revealing that [C _3-6-guan][TADC] had good thermal stability.In the second heating process of DSC, ([C _n-guan][TADC], n=3,4,5) experienced four kinds of phases, glassy, supercooled state, crystalline solid and liquid.

Original language	English
Pages (from-to)	19-22+31
Journal	Huozhayao Xuebao/Chinese Journal of Explosives and Propellants
Volume	35
Issue number	1
Publication status	Published - Feb 2012

Keywords

Energetic ionic liquids
Hexaalkylguanidinium TADC
Organic chemistry
Synthesis
Thermal properties

Cite this

@article{ed2f28128d7040fb960aac3ada7eb3c8,

title = "Synthesis and characterization of hexaalkylguanidinium TADC energetic ionic liquids",

abstract = "Four kinds of hexaalkylguanidinium 4,5-dicyano-1,2,3-triazole([C n-guan][TADC], n=3,4,5,6) energetic ionic liquids were synthesized by an ion exchange technique.Their structures were identified by IR and 1HNMR.Their density, solubility, thermal properties were studied.Their structures were identifed by IR, 'HNMR, solubility were tested in common organic solvents, density were measured by surface interfacial tersion meter, thermal properties were studied through TG, DSC method.The results showed that hexaalkylguanidinium TADC ionic liquids had good solubility in most of organic solvents. The maximum decomposition temperature was about 370°C, revealing that [C 3-6-guan][TADC] had good thermal stability.In the second heating process of DSC, ([C n-guan][TADC], n=3,4,5) experienced four kinds of phases, glassy, supercooled state, crystalline solid and liquid.",

keywords = "Energetic ionic liquids, Hexaalkylguanidinium TADC, Organic chemistry, Synthesis, Thermal properties",

author = "Gan, {Zhi Yong} and Chai, {Chun Peng} and Luo, {Yun Jun} and Na Li",

year = "2012",

month = feb,

language = "English",

volume = "35",

pages = "19--22+31",

journal = "Huozhayao Xuebao/Chinese Journal of Explosives and Propellants",

issn = "1007-7812",

publisher = "China Ordnance Industry Corporation",

number = "1",

}

TY - JOUR

T1 - Synthesis and characterization of hexaalkylguanidinium TADC energetic ionic liquids

AU - Gan, Zhi Yong

AU - Chai, Chun Peng

AU - Luo, Yun Jun

AU - Li, Na

PY - 2012/2

Y1 - 2012/2

N2 - Four kinds of hexaalkylguanidinium 4,5-dicyano-1,2,3-triazole([C n-guan][TADC], n=3,4,5,6) energetic ionic liquids were synthesized by an ion exchange technique.Their structures were identified by IR and 1HNMR.Their density, solubility, thermal properties were studied.Their structures were identifed by IR, 'HNMR, solubility were tested in common organic solvents, density were measured by surface interfacial tersion meter, thermal properties were studied through TG, DSC method.The results showed that hexaalkylguanidinium TADC ionic liquids had good solubility in most of organic solvents. The maximum decomposition temperature was about 370°C, revealing that [C 3-6-guan][TADC] had good thermal stability.In the second heating process of DSC, ([C n-guan][TADC], n=3,4,5) experienced four kinds of phases, glassy, supercooled state, crystalline solid and liquid.

AB - Four kinds of hexaalkylguanidinium 4,5-dicyano-1,2,3-triazole([C n-guan][TADC], n=3,4,5,6) energetic ionic liquids were synthesized by an ion exchange technique.Their structures were identified by IR and 1HNMR.Their density, solubility, thermal properties were studied.Their structures were identifed by IR, 'HNMR, solubility were tested in common organic solvents, density were measured by surface interfacial tersion meter, thermal properties were studied through TG, DSC method.The results showed that hexaalkylguanidinium TADC ionic liquids had good solubility in most of organic solvents. The maximum decomposition temperature was about 370°C, revealing that [C 3-6-guan][TADC] had good thermal stability.In the second heating process of DSC, ([C n-guan][TADC], n=3,4,5) experienced four kinds of phases, glassy, supercooled state, crystalline solid and liquid.

KW - Energetic ionic liquids

KW - Hexaalkylguanidinium TADC

KW - Organic chemistry

KW - Synthesis

KW - Thermal properties

UR - http://www.scopus.com/inward/record.url?scp=84860190883&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:84860190883

SN - 1007-7812

VL - 35

SP - 19-22+31

JO - Huozhayao Xuebao/Chinese Journal of Explosives and Propellants

JF - Huozhayao Xuebao/Chinese Journal of Explosives and Propellants

IS - 1

ER -

Synthesis and characterization of hexaalkylguanidinium TADC energetic ionic liquids

Abstract

Keywords

Other files and links

Fingerprint

Cite this