Poly[[aqua(1-aza-4-azoniabicyclo[2.2.2]octane)-cadmate(II)] -μ-5-sulfatoisophthalato]

Jun Tao, Xin Yin, Rong Bin Huang, Lan Sun Zheng, Seik Weng Ng*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

In the title compound, [Cd(C8H3O7S)(C 6H13N2)(H2O)]n, the Cd atom is coordinated by one O atom of a carboxylate group of a 5-sulfatoisophthalato ligand, two O atoms of the carboxylate group group of an adjacent symmetry-related 5-sulfoisophthalato entity, one O atom of the sulfonyl group of yet another adjacent 5-sulfatooisophthalato entity, a water molecule and the N atom of the 1-aza-4-azoniabicyclo[2.2.2]-octane cation in a six-coordinate octahedral geometry. Thus, the mode of coordination of the 5-sulfatoisophthalato ligand leads to the formation of a linear ribbon motif; adjacent ribbons are linked by hydrogen-bonding interactions, giving rise to a three-dimensional network structure.

Original languageEnglish
Pages (from-to)m473-m475
JournalActa Crystallographica Section E: Structure Reports Online
Volume59
Issue number7
DOIs
Publication statusPublished - Jul 2003
Externally publishedYes

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