TY - JOUR
T1 - Poly[[aqua(1-aza-4-azoniabicyclo[2.2.2]octane)-cadmate(II)] -μ-5-sulfatoisophthalato]
AU - Tao, Jun
AU - Yin, Xin
AU - Huang, Rong Bin
AU - Zheng, Lan Sun
AU - Ng, Seik Weng
PY - 2003/7
Y1 - 2003/7
N2 - In the title compound, [Cd(C8H3O7S)(C 6H13N2)(H2O)]n, the Cd atom is coordinated by one O atom of a carboxylate group of a 5-sulfatoisophthalato ligand, two O atoms of the carboxylate group group of an adjacent symmetry-related 5-sulfoisophthalato entity, one O atom of the sulfonyl group of yet another adjacent 5-sulfatooisophthalato entity, a water molecule and the N atom of the 1-aza-4-azoniabicyclo[2.2.2]-octane cation in a six-coordinate octahedral geometry. Thus, the mode of coordination of the 5-sulfatoisophthalato ligand leads to the formation of a linear ribbon motif; adjacent ribbons are linked by hydrogen-bonding interactions, giving rise to a three-dimensional network structure.
AB - In the title compound, [Cd(C8H3O7S)(C 6H13N2)(H2O)]n, the Cd atom is coordinated by one O atom of a carboxylate group of a 5-sulfatoisophthalato ligand, two O atoms of the carboxylate group group of an adjacent symmetry-related 5-sulfoisophthalato entity, one O atom of the sulfonyl group of yet another adjacent 5-sulfatooisophthalato entity, a water molecule and the N atom of the 1-aza-4-azoniabicyclo[2.2.2]-octane cation in a six-coordinate octahedral geometry. Thus, the mode of coordination of the 5-sulfatoisophthalato ligand leads to the formation of a linear ribbon motif; adjacent ribbons are linked by hydrogen-bonding interactions, giving rise to a three-dimensional network structure.
UR - http://www.scopus.com/inward/record.url?scp=1642449391&partnerID=8YFLogxK
U2 - 10.1107/S1600536803013230
DO - 10.1107/S1600536803013230
M3 - Article
AN - SCOPUS:1642449391
SN - 1600-5368
VL - 59
SP - m473-m475
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 7
ER -