Palladium(0)-catalyzed hydroalkoxylation of hexafluoropropene: Synthesis of hydrofluoroethers under neutral conditions

Yasuhisa Matsukawa; Junji Mizukado; Heng Dao Quan; Masanori Tamara; Akira Sekiya

doi:10.1002/anie.200462200

Palladium(0)-catalyzed hydroalkoxylation of hexafluoropropene: Synthesis of hydrofluoroethers under neutral conditions

Yasuhisa Matsukawa^*, Junji Mizukado, Heng Dao Quan, Masanori Tamara, Akira Sekiya

^*Corresponding author for this work

National Institute of Advanced Industrial Science and Technology

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

No vinyl ether by-products are formed in the palladium(0)-complex catalyzed hydroalkoxylation of hexafluoropropene (see scheme). Saturated hydrofluoro-ethers are selectively synthesized with alcohols or phenols under neutral conditions in the presence of [Pd(PPh₃)₄]/dppb. dppb = 1,4-bis(diphenylphosphanyl) butane.

Original language	English
Pages (from-to)	1128-1130
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	44
Issue number	7
DOIs	https://doi.org/10.1002/anie.200462200
Publication status	Published - 4 Feb 2005
Externally published	Yes

Keywords

Alcohols
Fluorinated alkenes
Green chemistry
Hydroalkoxylation
Palladium

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10.1002/anie.200462200

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abstract = "No vinyl ether by-products are formed in the palladium(0)-complex catalyzed hydroalkoxylation of hexafluoropropene (see scheme). Saturated hydrofluoro-ethers are selectively synthesized with alcohols or phenols under neutral conditions in the presence of [Pd(PPh3)4]/dppb. dppb = 1,4-bis(diphenylphosphanyl) butane.",

keywords = "Alcohols, Fluorinated alkenes, Green chemistry, Hydroalkoxylation, Palladium",

author = "Yasuhisa Matsukawa and Junji Mizukado and Quan, {Heng Dao} and Masanori Tamara and Akira Sekiya",

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AU - Matsukawa, Yasuhisa

AU - Mizukado, Junji

AU - Quan, Heng Dao

AU - Tamara, Masanori

AU - Sekiya, Akira

PY - 2005/2/4

Y1 - 2005/2/4

N2 - No vinyl ether by-products are formed in the palladium(0)-complex catalyzed hydroalkoxylation of hexafluoropropene (see scheme). Saturated hydrofluoro-ethers are selectively synthesized with alcohols or phenols under neutral conditions in the presence of [Pd(PPh3)4]/dppb. dppb = 1,4-bis(diphenylphosphanyl) butane.

AB - No vinyl ether by-products are formed in the palladium(0)-complex catalyzed hydroalkoxylation of hexafluoropropene (see scheme). Saturated hydrofluoro-ethers are selectively synthesized with alcohols or phenols under neutral conditions in the presence of [Pd(PPh3)4]/dppb. dppb = 1,4-bis(diphenylphosphanyl) butane.

KW - Alcohols

KW - Fluorinated alkenes

KW - Green chemistry

KW - Hydroalkoxylation

KW - Palladium

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U2 - 10.1002/anie.200462200

DO - 10.1002/anie.200462200

M3 - Article

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JF - Angewandte Chemie - International Edition

IS - 7

ER -

Palladium(0)-catalyzed hydroalkoxylation of hexafluoropropene: Synthesis of hydrofluoroethers under neutral conditions

Abstract

Keywords

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