Na1.5Cs0.5[Al{BO3}{B9O15(OH)3}1/3]: An Acentric Layered Aluminoborate with Nonlinear-Optical Properties

Chong An Chen; Guo Yu Yang

doi:10.1021/acs.inorgchem.3c02539

Na_1.5Cs_0.5[Al{BO₃}{B₉O₁₅(OH)₃}_1/3]: An Acentric Layered Aluminoborate with Nonlinear-Optical Properties

Chong An Chen, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

An acentric aluminoborate (ABO), Na_1.5Cs_0.5[Al{BO₃}{B₉O₁₅(OH)₃}_1/3] (1), has been made under solvothermal conditions. The alternations of AlO₄ tetrahedra and BO₃ triangles first build up the 2D ABO layer with 6-MR (membered-ring) windows. The fanlike B₉O₁₅(OH)₃ cluster adorns the layer through Al-O-B linkages, producing a pair of unclosed channels with 7-MR aperture on the lateral side of the layers. The novel B₉O₁₅(OH)₃ cluster represents the largest oxoboron cluster in the acentric ABO family. 1 not only shows a moderate second-harmonic-generation response of 1.2 times that of potassium dihydrogen phosphate but also has a short cutoff edge below 200 nm, indicating its potential applications in deep-UV regions.

Original language	English
Pages (from-to)	14163-14167
Number of pages	5
Journal	Inorganic Chemistry
Volume	62
Issue number	35
DOIs	https://doi.org/10.1021/acs.inorgchem.3c02539
Publication status	Published - 4 Sept 2023

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title = "Na1.5Cs0.5[Al{BO3}{B9O15(OH)3}1/3]: An Acentric Layered Aluminoborate with Nonlinear-Optical Properties",

abstract = "An acentric aluminoborate (ABO), Na1.5Cs0.5[Al{BO3}{B9O15(OH)3}1/3] (1), has been made under solvothermal conditions. The alternations of AlO4 tetrahedra and BO3 triangles first build up the 2D ABO layer with 6-MR (membered-ring) windows. The fanlike B9O15(OH)3 cluster adorns the layer through Al-O-B linkages, producing a pair of unclosed channels with 7-MR aperture on the lateral side of the layers. The novel B9O15(OH)3 cluster represents the largest oxoboron cluster in the acentric ABO family. 1 not only shows a moderate second-harmonic-generation response of 1.2 times that of potassium dihydrogen phosphate but also has a short cutoff edge below 200 nm, indicating its potential applications in deep-UV regions.",

author = "Chen, {Chong An} and Yang, {Guo Yu}",

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T1 - Na1.5Cs0.5[Al{BO3}{B9O15(OH)3}1/3]

T2 - An Acentric Layered Aluminoborate with Nonlinear-Optical Properties

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AU - Yang, Guo Yu

PY - 2023/9/4

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N2 - An acentric aluminoborate (ABO), Na1.5Cs0.5[Al{BO3}{B9O15(OH)3}1/3] (1), has been made under solvothermal conditions. The alternations of AlO4 tetrahedra and BO3 triangles first build up the 2D ABO layer with 6-MR (membered-ring) windows. The fanlike B9O15(OH)3 cluster adorns the layer through Al-O-B linkages, producing a pair of unclosed channels with 7-MR aperture on the lateral side of the layers. The novel B9O15(OH)3 cluster represents the largest oxoboron cluster in the acentric ABO family. 1 not only shows a moderate second-harmonic-generation response of 1.2 times that of potassium dihydrogen phosphate but also has a short cutoff edge below 200 nm, indicating its potential applications in deep-UV regions.

AB - An acentric aluminoborate (ABO), Na1.5Cs0.5[Al{BO3}{B9O15(OH)3}1/3] (1), has been made under solvothermal conditions. The alternations of AlO4 tetrahedra and BO3 triangles first build up the 2D ABO layer with 6-MR (membered-ring) windows. The fanlike B9O15(OH)3 cluster adorns the layer through Al-O-B linkages, producing a pair of unclosed channels with 7-MR aperture on the lateral side of the layers. The novel B9O15(OH)3 cluster represents the largest oxoboron cluster in the acentric ABO family. 1 not only shows a moderate second-harmonic-generation response of 1.2 times that of potassium dihydrogen phosphate but also has a short cutoff edge below 200 nm, indicating its potential applications in deep-UV regions.

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Na_1.5Cs_0.5[Al{BO₃}{B₉O₁₅(OH)₃}_1/3]: An Acentric Layered Aluminoborate with Nonlinear-Optical Properties

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