A spin-canted NiII4-based metal–organic framework with gas sorption properties and high adsorptive selectivity for light hydrocarbons

Jia Li, Ying Guo, Hong Ru Fu, Jian Zhang, Rong Bin Huang, Lan Sun Zheng, Jun Tao*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

29 Citations (Scopus)

Abstract

The reaction of nickel(ii) nitrate with isonicotinic acid and 2,6-dimethyl-pyridine-3,5-dicarboxylic acid affords a novel, tetranuclear nickel(ii)-based metal–organic framework that exhibits spin-canted antiferromagnetism with a canted angle of 1.65° and high adsorptive selectivity for light hydrocarbons.

Original languageEnglish
Pages (from-to)9161-9164
Number of pages4
JournalChemical Communications
Volume50
Issue number65
DOIs
Publication statusPublished - 17 Jul 2014
Externally publishedYes

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